Saturday, August 6, 2016

Crystals from Eggshells


Calcium crystals
The other day I was reading an article about using an egg drop activity to teach engineering to kindergarten students, based on the a design process derived from the Engineering is Elementary (EIE) curriculum, developed by the Boston Science museum. Though EIE does not have a specific egg drop activity, this is a good series for introducing engineering in elementary school. The article mentioned putting one of the eggs in vinegar to show that there was a chemical reaction.  This chemical reaction activity in the article was really just bolted onto the egg drop and not really scaffolded for K students, but it did remind me of an activity I hadn’t done in a while – making calcium crystals from dissolved egg shells.

This activity is pretty simple.  All you need is a washed, empty eggshell; some plain, white vinegar; a glass tumbler to hold the dissolving shell, and a pie plate or other broad, flat dish for growing your crystals. I took an eggshell from my breakfast, washed it out with water, and put it in an old jelly glass. I broke mine into smaller pieces so it would react and dissolve faster. Then I poured on enough plain white vinegar to cover it.  Any vinegar should work, but plain vinegar will make it easier to watch the reaction.

As soon as you pour the vinegar over the eggshell, you’ll see carbon dioxide bubbles coming off the shell as the acid reacts to the shell’s calcium carbonate. After a couple of days, a white inner coating from the shell will slide off and you can discard it. Let the shell sit in the vinegar for about 5-7 days until it is mostly dissolved. Once you are down to just a few fragments, you then run it through a fine kitchen strainer or even a coffee filter to take out those remaining bits of shell.  Pour the vinegar-calcium solution into a pie pan or some other broad shallow dish so it will evaporate quickly.  You’ll get better crystals if you let it evaporate slowly.  I put mine in a closet and left it for another week or so until it is all evaporated.  These are the crystals I got in the photos.
Pie plate for evaporation
 This can definitely lead to a whole new set of investigations about crystal and  all the ways you can make crystals with household stuff.

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